 Entering Gaussian System, Link 0=g16
 Initial command:
 /home/jzzeng/soft/g16/l1.exe "/home/jzzeng/test/Gau-15026.inp" -scrdir="/home/jzzeng/test/"
 Entering Link 1 = /home/jzzeng/soft/g16/l1.exe PID=     15028.
  
 Copyright (c) 1988,1990,1992,1993,1995,1998,2003,2009,2016,
            Gaussian, Inc.  All Rights Reserved.
  
 This is part of the Gaussian(R) 16 program.  It is based on
 the Gaussian(R) 09 system (copyright 2009, Gaussian, Inc.),
 the Gaussian(R) 03 system (copyright 2003, Gaussian, Inc.),
 the Gaussian(R) 98 system (copyright 1998, Gaussian, Inc.),
 the Gaussian(R) 94 system (copyright 1995, Gaussian, Inc.),
 the Gaussian 92(TM) system (copyright 1992, Gaussian, Inc.),
 the Gaussian 90(TM) system (copyright 1990, Gaussian, Inc.),
 the Gaussian 88(TM) system (copyright 1988, Gaussian, Inc.),
 the Gaussian 86(TM) system (copyright 1986, Carnegie Mellon
 University), and the Gaussian 82(TM) system (copyright 1983,
 Carnegie Mellon University). Gaussian is a federally registered
 trademark of Gaussian, Inc.
  
 This software contains proprietary and confidential information,
 including trade secrets, belonging to Gaussian, Inc.
  
 This software is provided under written license and may be
 used, copied, transmitted, or stored only in accord with that
 written license.
  
 The following legend is applicable only to US Government
 contracts under FAR:
  
                    RESTRICTED RIGHTS LEGEND
  
 Use, reproduction and disclosure by the US Government is
 subject to restrictions as set forth in subparagraphs (a)
 and (c) of the Commercial Computer Software - Restricted
 Rights clause in FAR 52.227-19.
  
 Gaussian, Inc.
 340 Quinnipiac St., Bldg. 40, Wallingford CT 06492
  
  
 ---------------------------------------------------------------
 Warning -- This program may not be used in any manner that
 competes with the business of Gaussian, Inc. or will provide
 assistance to any competitor of Gaussian, Inc.  The licensee
 of this program is prohibited from giving any competitor of
 Gaussian, Inc. access to this program.  By using this program,
 the user acknowledges that Gaussian, Inc. is engaged in the
 business of creating and licensing software in the field of
 computational chemistry and represents and warrants to the
 licensee that it is not a competitor of Gaussian, Inc. and that
 it will not use this program in any manner prohibited above.
 ---------------------------------------------------------------
  

 Cite this work as:
 Gaussian 16, Revision A.03,
 M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, 
 M. A. Robb, J. R. Cheeseman, G. Scalmani, V. Barone, 
 G. A. Petersson, H. Nakatsuji, X. Li, M. Caricato, A. V. Marenich, 
 J. Bloino, B. G. Janesko, R. Gomperts, B. Mennucci, H. P. Hratchian, 
 J. V. Ortiz, A. F. Izmaylov, J. L. Sonnenberg, D. Williams-Young, 
 F. Ding, F. Lipparini, F. Egidi, J. Goings, B. Peng, A. Petrone, 
 T. Henderson, D. Ranasinghe, V. G. Zakrzewski, J. Gao, N. Rega, 
 G. Zheng, W. Liang, M. Hada, M. Ehara, K. Toyota, R. Fukuda, 
 J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, 
 T. Vreven, K. Throssell, J. A. Montgomery, Jr., J. E. Peralta, 
 F. Ogliaro, M. J. Bearpark, J. J. Heyd, E. N. Brothers, K. N. Kudin, 
 V. N. Staroverov, T. A. Keith, R. Kobayashi, J. Normand, 
 K. Raghavachari, A. P. Rendell, J. C. Burant, S. S. Iyengar, 
 J. Tomasi, M. Cossi, J. M. Millam, M. Klene, C. Adamo, R. Cammi, 
 J. W. Ochterski, R. L. Martin, K. Morokuma, O. Farkas, 
 J. B. Foresman, and D. J. Fox, Gaussian, Inc., Wallingford CT, 2016.
 
 ******************************************
 Gaussian 16:  ES64L-G16RevA.03 25-Dec-2016
                25-Jun-2019 
 ******************************************
 %nproc=28
 Will use up to   28 processors via shared memory.
 --------------------
 #force b3lyp/6-31g**
 --------------------
 1/10=7,30=1,38=1/1,3;
 2/12=2,17=6,18=5,40=1/2;
 3/5=1,6=6,7=101,11=2,25=1,30=1,71=1,74=-5/1,2,3;
 4//1;
 5/5=2,38=5/2;
 6/7=2,8=2,9=2,10=2,28=1/1;
 7/29=1/1,2,3,16;
 1/10=7,30=1/3;
 99//99;
 -------
 methane
 -------
 Symbolic Z-matrix:
 Charge =  0 Multiplicity = 1
 C                     1.07422  -0.06034   0.02917 
 H                     2.16642  -0.06034   0.02917 
 H                     0.71015  -0.92887  -0.52401 
 H                     0.71015   0.85299  -0.44641 
 H                     0.71015  -0.10514   1.05793 
 

 GradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGrad
 Berny optimization.
 Initialization pass.
 Trust Radius=3.00D-01 FncErr=1.00D-07 GrdErr=1.00D-07 EigMax=2.50D+02 EigMin=1.00D-04
 Number of steps in this run=      2 maximum allowed number of steps=      2.
 GradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGrad

                          Input orientation:                          
 ---------------------------------------------------------------------
 Center     Atomic      Atomic             Coordinates (Angstroms)
 Number     Number       Type             X           Y           Z
 ---------------------------------------------------------------------
      1          6           0        1.074220   -0.060340    0.029170
      2          1           0        2.166420   -0.060340    0.029170
      3          1           0        0.710150   -0.928870   -0.524010
      4          1           0        0.710150    0.852990   -0.446410
      5          1           0        0.710150   -0.105140    1.057930
 ---------------------------------------------------------------------
                    Distance matrix (angstroms):
                    1          2          3          4          5
     1  C    0.000000
     2  H    1.092200   0.000000
     3  H    1.092199   1.783557   0.000000
     4  H    1.092197   1.783556   1.783549   0.000000
     5  H    1.092200   1.783557   1.783554   1.783550   0.000000
 Stoichiometry    CH4
 Framework group  C1[X(CH4)]
 Deg. of freedom     9
 Full point group                 C1      NOp   1
 Largest Abelian subgroup         C1      NOp   1
 Largest concise Abelian subgroup C1      NOp   1
                         Standard orientation:                         
 ---------------------------------------------------------------------
 Center     Atomic      Atomic             Coordinates (Angstroms)
 Number     Number       Type             X           Y           Z
 ---------------------------------------------------------------------
      1          6           0       -0.000001    0.000000    0.000000
      2          1           0       -1.092201    0.000000    0.000000
      3          1           0        0.364069   -0.813864   -0.630855
      4          1           0        0.364069   -0.139406    1.020252
      5          1           0        0.364069    0.953270   -0.389397
 ---------------------------------------------------------------------
 Rotational constants (GHZ):         157.6380023         157.6375616         157.6370163
 Standard basis: 6-31G(d,p) (6D, 7F)
 There are    35 symmetry adapted cartesian basis functions of A   symmetry.
 There are    35 symmetry adapted basis functions of A   symmetry.
    35 basis functions,    56 primitive gaussians,    35 cartesian basis functions
     5 alpha electrons        5 beta electrons
       nuclear repulsion energy        13.4083363407 Hartrees.
 NAtoms=    5 NActive=    5 NUniq=    5 SFac= 1.00D+00 NAtFMM=   60 NAOKFM=F Big=F
 Integral buffers will be    131072 words long.
 Raffenetti 2 integral format.
 Two-electron integral symmetry is turned on.
 One-electron integrals computed using PRISM.
 NBasis=    35 RedAO= T EigKep=  1.79D-02  NBF=    35
 NBsUse=    35 1.00D-06 EigRej= -1.00D+00 NBFU=    35
 ExpMin= 1.61D-01 ExpMax= 3.05D+03 ExpMxC= 4.57D+02 IAcc=3 IRadAn=         5 AccDes= 0.00D+00
 Harris functional with IExCor=  402 and IRadAn=       5 diagonalized for initial guess.
 HarFok:  IExCor=  402 AccDes= 0.00D+00 IRadAn=         5 IDoV= 1 UseB2=F ITyADJ=14
 ICtDFT=  3500011 ScaDFX=  1.000000  1.000000  1.000000  1.000000
 FoFCou: FMM=F IPFlag=           0 FMFlag=      100000 FMFlg1=           0
         NFxFlg=           0 DoJE=T BraDBF=F KetDBF=T FulRan=T
         wScrn=  0.000000 ICntrl=       500 IOpCl=  0 I1Cent=   200000004 NGrid=           0
         NMat0=    1 NMatS0=      1 NMatT0=    0 NMatD0=    1 NMtDS0=    0 NMtDT0=    0
 Petite list used in FoFCou.
 Keep R1 ints in memory in canonical form, NReq=24354403.
 Requested convergence on RMS density matrix=1.00D-08 within 128 cycles.
 Requested convergence on MAX density matrix=1.00D-06.
 Requested convergence on             energy=1.00D-06.
 No special actions if energy rises.
 Integral accuracy reduced to 1.0D-05 until final iterations.
 Initial convergence to 1.0D-05 achieved.  Increase integral accuracy.
 SCF Done:  E(RB3LYP) =  -40.5240137309     A.U. after    8 cycles
            NFock=  8  Conv=0.23D-08     -V/T= 2.0111

 **********************************************************************

            Population analysis using the SCF density.

 **********************************************************************

 Orbital symmetries:
       Occupied  (A) (A) (A) (A) (A)
       Virtual   (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
                 (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A) (A)
                 (A) (A) (A) (A) (A) (A)
 The electronic state is 1-A.
 Alpha  occ. eigenvalues --  -10.16717  -0.69034  -0.38827  -0.38827  -0.38827
 Alpha virt. eigenvalues --    0.11818   0.17670   0.17670   0.17670   0.52921
 Alpha virt. eigenvalues --    0.52921   0.52921   0.87424   0.87424   0.87424
 Alpha virt. eigenvalues --    0.92208   1.10023   1.36345   1.36345   2.04806
 Alpha virt. eigenvalues --    2.04806   2.04806   2.05141   2.05142   2.05142
 Alpha virt. eigenvalues --    2.62952   2.62953   2.62953   2.91074   2.91074
 Alpha virt. eigenvalues --    3.11458   3.41994   3.41994   3.41994   4.42248
          Condensed to atoms (all electrons):
               1          2          3          4          5
     1  C    4.899051   0.392830   0.392830   0.392830   0.392830
     2  H    0.392830   0.573073  -0.027832  -0.027832  -0.027832
     3  H    0.392830  -0.027832   0.573075  -0.027833  -0.027832
     4  H    0.392830  -0.027832  -0.027833   0.573074  -0.027833
     5  H    0.392830  -0.027832  -0.027832  -0.027833   0.573075
 Mulliken charges:
               1
     1  C   -0.470371
     2  H    0.117593
     3  H    0.117593
     4  H    0.117593
     5  H    0.117593
 Sum of Mulliken charges =   0.00000
 Mulliken charges with hydrogens summed into heavy atoms:
               1
     1  C    0.000000
 Electronic spatial extent (au):  <R**2>=             35.4329
 Charge=              0.0000 electrons
 Dipole moment (field-independent basis, Debye):
    X=              0.0000    Y=             -0.0000    Z=              0.0000  Tot=              0.0000
 Quadrupole moment (field-independent basis, Debye-Ang):
   XX=             -8.2465   YY=             -8.2465   ZZ=             -8.2465
   XY=             -0.0000   XZ=              0.0000   YZ=              0.0000
 Traceless Quadrupole moment (field-independent basis, Debye-Ang):
   XX=              0.0000   YY=             -0.0000   ZZ=             -0.0000
   XY=             -0.0000   XZ=              0.0000   YZ=              0.0000
 Octapole moment (field-independent basis, Debye-Ang**2):
  XXX=             -0.7604  YYY=              0.2130  ZZZ=              0.4937  XYY=              0.3802
  XXY=             -0.0000  XXZ=              0.0000  XZZ=              0.3802  YZZ=             -0.2130
  YYZ=             -0.4937  XYZ=              0.0000
 Hexadecapole moment (field-independent basis, Debye-Ang**3):
 XXXX=            -14.9429 YYYY=            -15.1704 ZZZZ=            -15.1704 XXXY=             -0.0000
 XXXZ=              0.0000 YYYX=              0.1275 YYYZ=              0.0000 ZZZX=              0.2954
 ZZZY=             -0.0000 XXYY=             -5.2843 XXZZ=             -5.2843 YYZZ=             -5.0568
 XXYZ=              0.0000 YYXZ=             -0.2954 ZZXY=             -0.1275
 N-N= 1.340833634068D+01 E-N=-1.198747475070D+02  KE= 4.007727827872D+01
 Calling FoFJK, ICntrl=      2127 FMM=F ISym2X=0 I1Cent= 0 IOpClX= 0 NMat=1 NMatS=1 NMatT=0.
 ***** Axes restored to original set *****
 -------------------------------------------------------------------
 Center     Atomic                   Forces (Hartrees/Bohr)
 Number     Number              X              Y              Z
 -------------------------------------------------------------------
      1        6          -0.000000623   -0.000000654    0.000000794
      2        1          -0.000215948   -0.000000016   -0.000000010
      3        1           0.000072325    0.000170842    0.000109258
      4        1           0.000071925   -0.000178640    0.000093176
      5        1           0.000072322    0.000008469   -0.000203220
 -------------------------------------------------------------------
 Cartesian Forces:  Max     0.000215948 RMS     0.000111163

 GradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGrad
 Berny optimization.
 Search for a local minimum.
 Step number   1 out of a maximum of    2
 All quantities printed in internal units (Hartrees-Bohrs-Radians)
 Second derivative matrix not updated -- first step.
 The second derivative matrix:
                          X1        Y1        Z1        X2        Y2
           X1           0.66422
           Y1          -0.00000   0.66422
           Z1           0.00000  -0.00000   0.66422
           X2          -0.34560  -0.00000   0.00000   0.34560
           Y2          -0.00000  -0.07628  -0.00000   0.00000   0.05678
           Z2           0.00000  -0.00000  -0.07628  -0.00000   0.00000
           X3          -0.10621  -0.07139  -0.04547  -0.00000  -0.02998
           Y3          -0.07139  -0.24659  -0.10847   0.00000   0.00907
           Z3          -0.04547  -0.10847  -0.14537   0.00000   0.00550
           X4          -0.10621   0.07507  -0.03909  -0.00000   0.03153
           Y4           0.07507  -0.26461   0.09806  -0.00000   0.00998
           Z4          -0.03909   0.09806  -0.12735   0.00000  -0.00497
           X5          -0.10621  -0.00368   0.08456   0.00000  -0.00155
           Y5          -0.00368  -0.07674   0.01040  -0.00000   0.00046
           Z5           0.08456   0.01041  -0.31522   0.00000  -0.00053
                          Z2        X3        Y3        Z3        X4
           Z2           0.05678
           X3          -0.01910   0.08887
           Y3           0.00550   0.07656   0.23942
           Z3           0.00394   0.04876   0.11633   0.13087
           X4          -0.01642   0.00867  -0.01076   0.01119   0.08887
           Y4          -0.00497   0.00975  -0.01251   0.01323  -0.08051
           Z4           0.00302   0.01208  -0.01579   0.01685   0.04192
           X5           0.03551   0.00867   0.00559  -0.01448   0.00867
           Y5          -0.00053   0.01507   0.01062  -0.02659  -0.01533
           Z5           0.01255   0.00372   0.00244  -0.00628   0.00240
                          Y4        Z4        X5        Y5        Z5
           Y4           0.25875
           Z4          -0.10517   0.11154
           X5          -0.00431  -0.01491   0.08887
           Y5           0.00840   0.02787   0.00395   0.05726
           Z5          -0.00116  -0.00406  -0.09068  -0.01116   0.31302
 ITU=  0
     Eigenvalues ---    0.11268   0.11268   0.13515   0.13515   0.13515
     Eigenvalues ---    0.34560   0.81139   0.81139   0.81140
 Angle between quadratic step and forces=   0.37 degrees.
 Linear search not attempted -- first point.
 B after Tr=    -0.000001    0.000000   -0.000000
         Rot=    1.000000    0.000000   -0.000000   -0.000000 Ang=   0.00 deg.
 Variable       Old X    -DE/DX   Delta X   Delta X   Delta X     New X
                                 (Linear)    (Quad)   (Total)
    X1        2.02998  -0.00000   0.00000  -0.00000  -0.00000   2.02998
    Y1       -0.11403  -0.00000   0.00000   0.00000   0.00000  -0.11403
    Z1        0.05512   0.00000   0.00000  -0.00000  -0.00000   0.05512
    X2        4.09394  -0.00022   0.00000  -0.00063  -0.00063   4.09331
    Y2       -0.11403  -0.00000   0.00000  -0.00000  -0.00000  -0.11403
    Z2        0.05512  -0.00000   0.00000   0.00000  -0.00000   0.05512
    X3        1.34199   0.00007   0.00000   0.00021   0.00021   1.34220
    Y3       -1.75531   0.00017   0.00000   0.00049   0.00049  -1.75482
    Z3       -0.99024   0.00011   0.00000   0.00032   0.00032  -0.98992
    X4        1.34199   0.00007   0.00000   0.00021   0.00021   1.34220
    Y4        1.61192  -0.00018   0.00000  -0.00051  -0.00051   1.61140
    Z4       -0.84359   0.00009   0.00000   0.00027   0.00027  -0.84332
    X5        1.34199   0.00007   0.00000   0.00021   0.00021   1.34220
    Y5       -0.19869   0.00001   0.00000   0.00002   0.00002  -0.19866
    Z5        1.99920  -0.00020   0.00000  -0.00059  -0.00059   1.99861
         Item               Value     Threshold  Converged?
 Maximum Force            0.000216     0.000450     YES
 RMS     Force            0.000111     0.000300     YES
 Maximum Displacement     0.000628     0.001800     YES
 RMS     Displacement     0.000322     0.001200     YES
 Predicted change in Energy=-2.681743D-07
 Optimization completed.
    -- Stationary point found.
 GradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGradGrad

 1\1\GINC-LOCALHOST\Force\RB3LYP\6-31G(d,p)\C1H4\JZZENG\25-Jun-2019\0\\
 #force b3lyp/6-31g**\\methane\\0,1\C,1.07422,-0.06034,0.02917\H,2.1664
 2,-0.06034,0.02917\H,0.71015,-0.92887,-0.52401\H,0.71015,0.85299,-0.44
 641\H,0.71015,-0.10514,1.05793\\Version=ES64L-G16RevA.03\State=1-A\HF=
 -40.5240137\RMSD=2.291e-09\RMSF=1.112e-04\Dipole=-0.0000018,0.0000007,
 -0.0000007\Quadrupole=0.0000105,-0.0000083,-0.0000022,-0.000001,0.0000
 01,0.0000025\PG=C01 [X(C1H4)]\\@


 SEE YOU NOW,
 YOUR BAIT OF FALSEHOOD TAKES THIS CARP OF TRUTH.
 AND THUS DO WE OF WISDOM AND OF REACH...
 BY INDIRECTIONS FIND DIRECTIONS OUT.    -- HAMLET, II, 1
 Job cpu time:       0 days  0 hours  1 minutes 11.1 seconds.
 Elapsed time:       0 days  0 hours  0 minutes  3.2 seconds.
 File lengths (MBytes):  RWF=      6 Int=      0 D2E=      0 Chk=      1 Scr=      1
 Normal termination of Gaussian 16 at Tue Jun 25 00:14:07 2019.
